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EOM vs RPA vs RDM vs GW(?) strategies #68

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PaulWAyers opened this issue Feb 10, 2022 · 3 comments
Open

EOM vs RPA vs RDM vs GW(?) strategies #68

PaulWAyers opened this issue Feb 10, 2022 · 3 comments

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@PaulWAyers
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PaulWAyers commented Feb 10, 2022

What is the relationship between these different strategies for generating the correlation energy.

GW approximation is closely related to RPA.
RPA is closely related to EOM/response.
EOM response is closely related to adiabatic connection approach.

Exactly what are the relationships?

Three different ways of deriving pp-RPA are referenced in
https://aip.scitation.org/doi/10.1063/1.4977928

Link between GW and RPA
https://aip.scitation.org/doi/10.1063/1.5128415
https://journals.aps.org/prb/abstract/10.1103/PhysRevB.91.165110
https://journals.aps.org/pra/pdf/10.1103/PhysRevA.82.032502
https://www.tddft.org/TDDFT2010/workshop/dobson.pdf
https://arxiv.org/pdf/1506.01737.pdf (maybe)
https://www.nature.com/articles/s41524-019-0242-8.pdf?proof=t (maybe)

Trace vs. other formula:
https://www.frontiersin.org/articles/10.3389/fchem.2021.751054/full
https://pubs.acs.org/doi/10.1021/ct200501r

@PaulWAyers
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The following paper may explain this a little bit?
ct200501r.pdf

@PaulWAyers
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  1. Lehman representation (Green's Function). Key link between RPA, EOM, and GF methods.
  2. Tamm-Damcoff approximation vs. truncating the right-hand-side.
  3. What are all the relationships (and equivalencies) between methods in general.

@PaulWAyers
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See also https://arxiv.org/abs/2212.08982

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