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{ | ||
"reactions": [ | ||
{ | ||
"monomers": [ | ||
"Methacrylic acid", | ||
"Styrene" | ||
], | ||
"reaction_conditions": [ | ||
{ | ||
"polymerization_type": "free radical", | ||
"solvent": "carbon tetrachloride", | ||
"method": "solvent", | ||
"temperature": 60.0, | ||
"temperature_unit": "°C", | ||
"reaction_constants": { | ||
"constant_1": 0.54, | ||
"constant_2": 0.06 | ||
}, | ||
"reaction_constant_conf": { | ||
"constant_conf_1": 0.01, | ||
"constant_conf_2": 0.03 | ||
}, | ||
"determination_method": "Kelen-Tudor" | ||
}, | ||
{ | ||
"polymerization_type": "free radical", | ||
"solvent": "chloroform", | ||
"method": "solvent", | ||
"temperature": 60.0, | ||
"temperature_unit": "°C", | ||
"reaction_constants": { | ||
"constant_1": 0.51, | ||
"constant_2": 0.08 | ||
}, | ||
"reaction_constant_conf": { | ||
"constant_conf_1": 0.01, | ||
"constant_conf_2": 0.03 | ||
}, | ||
"determination_method": "Kelen-Tudor" | ||
}, | ||
{ | ||
"polymerization_type": "free radical", | ||
"solvent": "acetone", | ||
"method": "solvent", | ||
"temperature": 60.0, | ||
"temperature_unit": "°C", | ||
"reaction_constants": { | ||
"constant_1": 0.43, | ||
"constant_2": 0.65 | ||
}, | ||
"reaction_constant_conf": { | ||
"constant_conf_1": 0.0, | ||
"constant_conf_2": 0.02 | ||
}, | ||
"determination_method": "Kelen-Tudor" | ||
}, | ||
{ | ||
"polymerization_type": "free radical", | ||
"solvent": "1,4-dioxane", | ||
"method": "solvent", | ||
"temperature": 60.0, | ||
"temperature_unit": "°C", | ||
"reaction_constants": { | ||
"constant_1": 0.41, | ||
"constant_2": 0.59 | ||
}, | ||
"reaction_constant_conf": { | ||
"constant_conf_1": 0.02, | ||
"constant_conf_2": 0.05 | ||
}, | ||
"determination_method": "Kelen-Tudor" | ||
}, | ||
{ | ||
"polymerization_type": "free radical", | ||
"solvent": "acetonitrile", | ||
"method": "solvent", | ||
"temperature": 60.0, | ||
"temperature_unit": "°C", | ||
"reaction_constants": { | ||
"constant_1": 0.06, | ||
"constant_2": 0.29 | ||
}, | ||
"reaction_constant_conf": { | ||
"constant_conf_1": 0.02, | ||
"constant_conf_2": 0.0 | ||
}, | ||
"determination_method": "Kelen-Tudor" | ||
} | ||
] | ||
} | ||
], | ||
"source": "https://doi.org/10.1002/macp.1985.021860810", | ||
"PDF_name": "The influence of molecular interaction on polymerization, 10", | ||
"source_pdf": "paper01.pdf" | ||
} |